The Non-ferrous Pyrometallurgy
Best Paper Award
2007 winner –
J. Liu and T.A. Utigard, for their paper entitled:
“Reduction
of nickel-copper matte/oxysulfide/slag”, published in the Canadian
Metallurgical Quarterly (Vol. 45, No 4 pp 379-394, 2006).
Abstract
To improve the value of recovered metals, a new operating concept for
the Inco flash furnace was investigated in which the flash furnace coke
addition practice aimed to establish a reducing barrier on the surface of
the molten bath. The descending partially oxidized sulfide mineral
particles would reach the supernatant coke layer prior to the formation of
slag. The key for success depends on the effectiveness of the coke layer to
produce a sulfur deficient matte while maintaining the furnace production
capacity.
The mechanism and rate of carbon reduction of the phases formed in
the flash flame (i.e., sulfide (matte) and oxysulfide) were investigated by
means of crucible graphite reduction tests. The objective of these tests was
to measure the rate of solid graphite reduction of matte, oxysulfide, slag
and matte+slag mixture at different temperatures. These tests were
expected to permit understanding and explain the reduction mechanism
of each material by comparing the respective reaction rates, product
reaction gas compositions, reduced material assays and other relevant
parameters. Direct visual inspection of the test crucibles would provide
additional information.

|